$ RUN SPIKE NBS*QUANT84-SPIKE Revision Date: 29 FEB 1984 Quantitative Analysis by the Spiking Method Written by R. L. Snyder and C. R. Hubbard Run on 4-AUG-85 at 22:03:58 Select Output Mode Desired: (Output is 132 characters wide) 1 - causes output to be put on the interactive terminal. newname - causes output to go to the named file. - causes output to go to a file named SPIKE.LIS. Enter the output destination: 1 Select a print control option (I1): 0 = Full listing of data files 1 = Heading on first data file only 2 = Data file titles only 2 Enter weighting choice: 0 for counting statistical weights 1 for unit weights 0 Enter Orig. Sample file name RS086D Title: 80SI:20AL203 (ZERO SPIKED); AM-2 JOHN J. SIMMINS Enter Orig.+ Spike file name RS081D Title: 80SI:20AL2O3 (ZERO SPIKED); AM-2 JOHN J. SIMMINS Enter Orig.+ Spike file name RS082D Title: 70SI:30AL203 (0.125 SPIKED); AM-2 JOHN J. SIMMINS Enter Orig.+ Spike file name RS083D Title: 60SI:40AL2O3 (0.250 SPIKED); AM-2 JOHN J. SIMMINS Enter Orig.+ Spike file name RS084D Title: 60SI:40AL203 (0.250 SPIKED); 2ND TRY; AM-2 JOHN J. SIMMINS Enter Orig.+ Spike file name RS085D Title: 50SI:50AL2O3 (0.375 SPIKING); AM-2 JOHN J. SIMMINS Enter Orig.+ Spike file name Line by Line Composition Analysis from Weighted Linear Regressions of 9 points per analysis Analyte Line Reference Line Weight Least Sqs Phase h k l Name h k l Percent est Std Dev Slope Intercept correlation AL2O3 1 0 4 SI 1 1 1 22.84 1.36 0.2364(0.0098) 0.0540(0.0023) 0.987 gms added Obs esd Calc Delta per gm Ia/Ir Ia/Ir Ia/Ir Ia/Ir 0.0000 0.0546 0.0013 0.0540 -0.0006 0.0000 0.0519 0.0013 0.0540 0.0021 0.0000 0.0550 0.0011 0.0540 -0.0010 0.1429 0.0879 0.0014 0.0878 -0.0001 0.1429 0.0911 0.0015 0.0878 -0.0033 0.3333 0.1172 0.0019 0.1328 0.0157 0.3333 0.1391 0.0018 0.1328 -0.0063 0.6000 0.2016 0.0023 0.1959 -0.0057 0.6000 0.1953 0.0023 0.1959 0.0005 AL2O3 1 1 0 SI 1 1 1 23.83 1.00 0.1079(0.0031) 0.0257(0.0008) 1.002 gms added Obs esd Calc Delta per gm Ia/Ir Ia/Ir Ia/Ir Ia/Ir 0.0000 0.0263 0.0011 0.0257 -0.0006 0.0000 0.0257 0.0011 0.0257 0.0001 0.0000 0.0249 0.0009 0.0257 0.0008 0.1429 0.0399 0.0011 0.0411 0.0013 0.1429 0.0426 0.0012 0.0411 -0.0015 0.3333 0.0615 0.0014 0.0617 0.0002 0.3333 0.0637 0.0014 0.0617 -0.0020 0.6000 0.0935 0.0017 0.0905 -0.0030 0.6000 0.0862 0.0016 0.0905 0.0043 AL2O3 1 1 3 SI 1 1 1 21.32 0.54 0.3065(0.0051) 0.0653(0.0012) 1.008 gms added Obs esd Calc Delta per gm Ia/Ir Ia/Ir Ia/Ir Ia/Ir 0.0000 0.0625 0.0017 0.0653 0.0029 0.0000 0.0653 0.0017 0.0653 0.0001 0.0000 0.0661 0.0015 0.0653 -0.0007 0.1429 0.1085 0.0020 0.1091 0.0007 0.1429 0.1103 0.0020 0.1091 -0.0011 0.3333 0.1687 0.0024 0.1675 -0.0012 0.3333 0.1742 0.0024 0.1675 -0.0067 0.6000 0.2436 0.0030 0.2492 0.0056 0.6000 0.2477 0.0030 0.2492 0.0015 AL2O3 0 2 4 SI 1 1 1 23.07 0.72 0.1236(0.0026) 0.0285(0.0007) 1.001 gms added Obs esd Calc Delta per gm Ia/Ir Ia/Ir Ia/Ir Ia/Ir 0.0000 0.0292 0.0011 0.0285 -0.0007 0.0000 0.0285 0.0011 0.0285 0.0000 0.0000 0.0282 0.0010 0.0285 0.0004 0.1429 0.0437 0.0012 0.0462 0.0024 0.1429 0.0475 0.0012 0.0462 -0.0013 0.3333 0.0706 0.0015 0.0697 -0.0009 0.3333 0.0715 0.0015 0.0697 -0.0017 0.6000 0.1042 0.0017 0.1027 -0.0015 0.6000 0.1001 0.0017 0.1027 0.0026 AL2O3 1 0 4 SI 2 2 0 21.13 1.49 0.4308(0.0212) 0.0910(0.0046) 0.974 gms added Obs esd Calc Delta per gm Ia/Ir Ia/Ir Ia/Ir Ia/Ir 0.0000 0.0926 0.0022 0.0910 -0.0016 0.0000 0.0857 0.0021 0.0910 0.0053 0.0000 0.0956 0.0020 0.0910 -0.0046 0.1429 0.1553 0.0026 0.1526 -0.0028 0.1429 0.1536 0.0026 0.1526 -0.0011 0.3333 0.2021 0.0034 0.2346 0.0325 0.3333 0.2473 0.0035 0.2346 -0.0127 0.6000 0.3608 0.0046 0.3495 -0.0112 0.6000 0.3555 0.0046 0.3495 -0.0060 AL2O3 1 1 0 SI 2 2 0 21.87 0.76 0.1979(0.0046) 0.0433(0.0011) 0.997 gms added Obs esd Calc Delta per gm Ia/Ir Ia/Ir Ia/Ir Ia/Ir 0.0000 0.0446 0.0018 0.0433 -0.0013 0.0000 0.0424 0.0018 0.0433 0.0009 0.0000 0.0433 0.0017 0.0433 0.0000 0.1429 0.0705 0.0020 0.0716 0.0010 0.1429 0.0719 0.0020 0.0716 -0.0003 0.3333 0.1061 0.0024 0.1093 0.0032 0.3333 0.1133 0.0025 0.1093 -0.0040 0.6000 0.1673 0.0032 0.1621 -0.0053 0.6000 0.1568 0.0031 0.1621 0.0052 AL2O3 1 1 3 SI 2 2 0 19.62 0.60 0.5600(0.0113) 0.1099(0.0025) 1.001 gms added Obs esd Calc Delta per gm Ia/Ir Ia/Ir Ia/Ir Ia/Ir 0.0000 0.1059 0.0030 0.1099 0.0040 0.0000 0.1078 0.0029 0.1099 0.0021 0.0000 0.1149 0.0027 0.1099 -0.0050 0.1429 0.1918 0.0036 0.1899 -0.0019 0.1429 0.1860 0.0035 0.1899 0.0039 0.3333 0.2912 0.0044 0.2965 0.0054 0.3333 0.3095 0.0046 0.2965 -0.0130 0.6000 0.4360 0.0060 0.4459 0.0098 0.6000 0.4509 0.0061 0.4459 -0.0050 AL2O3 0 2 4 SI 2 2 0 21.20 0.51 0.2265(0.0036) 0.0480(0.0009) 0.996 gms added Obs esd Calc Delta per gm Ia/Ir Ia/Ir Ia/Ir Ia/Ir 0.0000 0.0494 0.0018 0.0480 -0.0014 0.0000 0.0471 0.0018 0.0480 0.0009 0.0000 0.0490 0.0017 0.0480 -0.0009 0.1429 0.0773 0.0021 0.0804 0.0031 0.1429 0.0801 0.0021 0.0804 0.0003 0.3333 0.1219 0.0026 0.1235 0.0017 0.3333 0.1270 0.0027 0.1235 -0.0035 0.6000 0.1865 0.0033 0.1840 -0.0025 0.6000 0.1821 0.0033 0.1840 0.0018 Average and weighted average for each analyte lines: Analyte Line Reference Line Average Root Mean Waverage Weighted Weighted # of Phase h k l Name h k l Wt % Square Dev. Wt % e.s.d. Rms Dev. Analyses AL2O3 1 0 4 all all 21.98 1.21 22.07 1.00 0.86 2 AL2O3 1 1 0 all all 22.85 1.39 22.59 0.60 0.98 2 AL2O3 1 1 3 all all 20.47 1.21 20.56 0.40 0.85 2 AL2O3 0 2 4 all all 22.13 1.32 21.82 0.42 0.93 2 Overall average and weighted average: Analyte Line Reference Line Average Root Mean Waverage Weighted Weighted # of Phase h k l Name h k l Wt % Square Dev. Wt % e.s.d. Rms Dev. Analyses AL2O3 all all all 21.86 1.34 21.47 0.25 0.47 8 $